典型文献
Synthesis of pyrimidines from dinitrogen and carbon
文献摘要：
The element nitrogen and nitrogenous compounds are vital to life.The synthesis of nitrogen-containing compounds using dinitrogen as the nitrogen source,not through ammonia,is of great interest and great value but remains a grand challenge.Herein,we describe a strategy to realize this transformation by combining the heterogeneous approach with the homogeneous methodology.The N2 molecule was first fixed with carbon and LiH through a one-pot heterogeneous process,forming Li2CN2 as an'activated'nitrogen source with high efficiency.Then subsequent homogeneous treatments of Li2CN2 to construct the organic synthon carbodiimide and the RNA/DNA building block pyrimidines were fulfilled.By using 15N2 as the feedstock,their corresponding 15N-labeled carbodiimide and pyrimidines were readily obtained.This homogeneous-heterogeneous synergy strategy will open a new chapter for N2 transformation.
文献关键词：
中图分类号：
作者姓名：
Xianghui Shi;Qianru Wang;Chao Qin;Li-Jun Wu;Yuanjin Chen;Gao-Xiang Wang;Yongli Cai;Wenbo Gao;Teng He;Junnian Wei;Jianping Guo;Ping Chen;Zhenfeng Xi
作者机构：
Beijing National Laboratory for Molecular Sciences(BNLMS),Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education,College of Chemistry,Peking University,Beijing 100871,China;Dalian Institute of Chemical Physics,Chinese Academy of Sciences,Dalian 116023,China;University of Chinese Academy of Sciences,Beijing 100049,China;State Key Laboratory of Catalysis,Dalian Institute of Chemical Physics,Chinese Academy of Sciences,Dalian 116023,China
文献出处：
引用格式：
[1]Xianghui Shi;Qianru Wang;Chao Qin;Li-Jun Wu;Yuanjin Chen;Gao-Xiang Wang;Yongli Cai;Wenbo Gao;Teng He;Junnian Wei;Jianping Guo;Ping Chen;Zhenfeng Xi-.Synthesis of pyrimidines from dinitrogen and carbon)[J].国家科学评论（英文版）,2022(12):214-220
A类：
pyrimidines,LiH,Li2CN2,synthon
B类：
Synthesis,from,dinitrogen,carbon,element,nitrogenous,compounds,are,vital,life,synthesis,containing,using,source,not,through,ammonia,great,interest,value,but,remains,grand,challenge,Herein,describe,strategy,realize,this,transformation,by,combining,heterogeneous,approach,homogeneous,methodology,molecule,was,first,fixed,one,pot,process,forming,activated,high,efficiency,Then,subsequent,treatments,construct,organic,carbodiimide,building,block,were,fulfilled,By,15N2,feedstock,their,corresponding,labeled,readily,obtained,This,synergy,will,open,new,chapter
AB值：
0.570246
相似文献
机标中图分类号，由域田数据科技根据网络公开资料自动分析生成，仅供学习研究参考。
