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典型文献
Ionic liquid-based electrolytes for CO2 electroreduction and CO2 electroorganic transformation
文献摘要:
CO2 is an abundant and renewable C1 feedstock.Electrochemical transformation of CO2 can integrate CO2 fixation with renewable electricity storage,providing an avenue to close the anthropogenic carbon cycle.As a new type of green and chemically tailorable solvent,ionic liquids(ILs)have been proposed as highly promising alternatives for conventional electrolytes in electrochemical CO2 conversion.This review summarizes major advances in the electrochemical transformation of CO2 into value-added carbonic fuels and chemicals in IL-based media in the past several years.Both the direct CO2 electroreduction(CO2ER)and CO2-involved electroorganic transformation(CO2EOT)are discussed,focusing on the effect of electrocatalysts,IL components,reactor configurations and operating conditions on catalytic activity,selectivity and reusability.The reasons for the enhanced CO2 conversion performance by ILs are also discussed,providing guidance for the rational design of novel IL-based electrochemical processes for CO2 conversion.Finally,the critical challenges remaining in this research area and promising directions for future research are proposed.
文献关键词:
作者姓名:
Xingxing Tan;Xiaofu Sun;Buxing Han
作者机构:
Beijing National Laboratory for Molecular Sciences,CAS Key Laboratory of Colloid and Interface and Thermodynamics,CAS Research/Education Center for Excellence in Molecular Sciences,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100190,China;School of Chemistry and Chemical Engineering,University of Chinese Academy of Sciences,Beijing 100049,China;Shanghai Key Laboratory of Green Chemistry and Chemical Processes,School of Chemistry and Molecular Engineering,East China Normal University,Shanghai 200062,China
引用格式:
[1]Xingxing Tan;Xiaofu Sun;Buxing Han-.Ionic liquid-based electrolytes for CO2 electroreduction and CO2 electroorganic transformation)[J].国家科学评论(英文版),2022(04):163-180
A类:
electroorganic,CO2EOT
B类:
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AB值:
0.61182
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