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典型文献
Studies on the effects of pre-firing and sintering temperature on NSDC nanocomposite electrolytes
文献摘要:
Solid oxide fuel cells(SOFCs)technology,with fuel flexibility,is one of the most promising power generation technology.However,the high operating temperature of SOFCs has hindered their commercial applications.As a crucial requirement to enhance its performance,SOFCs electrolytes should operate at a low temperature.Car-bonate/ceria composites are developed as electrolytes for low operating temperature SOFCs,and a better un-derstanding of the mechanism of its ionic conductivity serves this purpose.In this work,ceria-carbonate composite electrolyte,Na2CO3/samarium doped ceria(NSDC)were synthesized by the co-precipitation method.The synthesized electrolytes were characterized by X-ray diffraction(XRD),scanning electron microscopy(SEM),X-ray photoelectron spectroscopy(XPS),and UV-Vis spectroscopy.The XRD and SEM results showed that the sintered NSDC nanocomposite comprised a single-phase dense electrolyte structure.The crystallite size of the NSDC nanocomposite was greatly affected by the different pre-firing temperatures and different sintering tem-peratures.Also,the ionic conductivity of the prepared NSDC nanocomposite electrolytes was strongly dependent on the pre-firing and sintering temperatures.The NSDC nanocomposite electrolytes were pre-fired at 950℃and 650℃and sintered at 1200℃and 900℃respectively,had ionic conductivity in H2 and air high as 0.36 S/cm and 0.3 S/cm.
文献关键词:
作者姓名:
Saddam Hussain;Yangping Li;Fida Hussain Memon;Sabir Hussain;Lei Li;Khalid Hussain Thebo
作者机构:
State Key Laboratory of Solidification Processing,School of Materials Science and Engineering,Northwestern Polytechnical University,Xi'an,Shaanxi,710072,China;Department of Electrical Engineering,Sukkur IBA University,Sindh,Pakistan;Department of Space Science,University of the Punjab,Lahore,54590,Pakistan;University of Chinese Academy of Sciences,Haidian,Beijing 100190,China
引用格式:
[1]Saddam Hussain;Yangping Li;Fida Hussain Memon;Sabir Hussain;Lei Li;Khalid Hussain Thebo-.Studies on the effects of pre-firing and sintering temperature on NSDC nanocomposite electrolytes)[J].自然科学进展·国际材料(英文),2022(01):128-134
A类:
NSDC
B类:
Studies,effects,firing,sintering,nanocomposite,electrolytes,Solid,oxide,fuel,cells,SOFCs,technology,flexibility,one,most,promising,power,generation,However,high,operating,hindered,their,commercial,applications,crucial,requirement,enhance,its,performance,should,operate,low,Car,ceria,composites,developed,better,un,derstanding,mechanism,ionic,conductivity,serves,this,purpose,In,work,carbonate,Na2CO3,samarium,doped,were,synthesized,by,precipitation,method,characterized,ray,diffraction,scanning,microscopy,photoelectron,spectroscopy,XPS,UV,Vis,results,showed,that,sintered,comprised,single,phase,dense,structure,crystallite,was,greatly,affected,different,temperatures,Also,prepared,strongly,dependent,fired,respectively,had,H2,air
AB值:
0.467586
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