典型文献
Methods to Make Conductive Covalent Organic Frameworks for Electrocatalytic Applications
文献摘要：
Covalent organic frameworks(COFs)represent a new class of crystalline organic polymer materials with the characteristics of high specific surface area,uniform pore distribution,high porosity,low density,devisable chain structures and good structural stability.These collective features play an important role in creating highly efficient electrocatalysts for energy conversion and fuel generation.Recent years have witnessed considerable advances in COF-based electrocata-lysts for major electrocatalytic reactions such as oxygen reduction,oxygen evolution,hydrogen evolution,and reduction of carbon dioxide and nitrogen.However,it has been widely accepted that the poor electrical conductivity of most pristine COFs limits the further progress in electrocatalytic field.In this review,recent structural engineering strategies are summarized toward improving the electrical conductivity of COFs for achieving high performance.The researches of conductive COFs and their derivatives are described in detail.The structure-activity relationship between molecular structures of COFs and their electrocatalytic performance is emphasized.Lastly,current challenges and future perspectives on fabricating COFs as promising electrocatalysts are discussed.The purpose of this review is to provide guidelines for the preparation of highly efficient COF-based electrocatalytic materials with a view to re-placing the commercially available noble metal-based electrocatalysts.
文献关键词：
中图分类号：
作者姓名：
Mengyang Chen;Ye Zhou;Shi-Bin Ren;Jiong Wang
作者机构：
School of Pharmaceutical and Materials Engineering,Taizhou University,Taizhou 317000,China;State Key Laboratory of Inorganic Synthesis and Preparative Chemistry,College of Chemistry,Jilin University,Changchun 130012,China;Innovation Center for Chemical Sciences,College of Chemistry,Chemical Engineering and Materials Science,Soochow University,Suzhou 215123,China
文献出处：
引用格式：
[1]Mengyang Chen;Ye Zhou;Shi-Bin Ren;Jiong Wang-.Methods to Make Conductive Covalent Organic Frameworks for Electrocatalytic Applications)[J].结构化学,2022(12):107-119
A类：
devisable
B类：
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AB值：
0.62982
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