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典型文献
Thermoelectric performance of(AgBiTe2)1-x(SnTe)x with stable cubic enabled by enhanced configurational entropy
文献摘要:
ABX2(A=Ag,Na,Cu;B=Sb,Bi;X=S,Se,Te)(Groups Ⅰ-Ⅴ-Ⅵ2)compounds,which are all charac-terized by the ultralow lattice thermal conductivity because of their strong lattice anharmonicity caused by lone-pair electrons,have aroused wide attention in thermoelectric community.The practical application of thermoelectric devices usually requires both the compatible n-type and p-type materials simultaneously.However,most of Ⅰ-Ⅴ-Ⅵ2 compounds are intrinsic p-type semiconductors,lacking their n-type counterparts for thermoelectrics.Herein,in this work,we increase the configuration entropy of AgBiTe2 by alloying SnTe,in order to stabilize the cubic phase at room temperature.With further optimization of thermal and electrical performance,the thermoelectric performance could be improved simultaneously in both n-and p-type(AgBiTe2)1-x(SnTe)x(x=0.3,0.4)solid solutions.Finally,p-type compound with the nominal composition of(AgBi0.99Cd0.01Te2)0.6(SnTe)0.4 and n-type of(AgBiTe2)0.7(SnTe)0.3~Br 6%show the maximum zT of~0.33 and~0.21,at 381 and 423 K,respectively.
文献关键词:
作者姓名:
Ting Zhao;Li-Ze Yang;Yun Zhou;Hui-Jun Liao;Zheng-Yong Huang;Jian Li;Xu Lu;Xiao-Yuan Zhou
作者机构:
Chongqing Key Laboratory of Soft Condensed Matter Physics and Smart Materials,College of Physics,Chongqing University,Chongqing 401331,China;College of Ocean Science and Engineering,Shanghai Maritime University,Shanghai 201306,China;State Key Laboratory of Power Transmission Equipment&System Security and New Technology,Chongqing University,Chongqing 400030,China;Analytical and Testing Center,Chongqing University,Chongqing 401331,China
引用格式:
[1]Ting Zhao;Li-Ze Yang;Yun Zhou;Hui-Jun Liao;Zheng-Yong Huang;Jian Li;Xu Lu;Xiao-Yuan Zhou-.Thermoelectric performance of(AgBiTe2)1-x(SnTe)x with stable cubic enabled by enhanced configurational entropy)[J].稀有金属(英文版),2022(12):4149-4155
A类:
AgBiTe2,ABX2,AgBi0,99Cd0,01Te2
B类:
Thermoelectric,performance,SnTe,stable,cubic,enabled,by,enhanced,configurational,entropy,Na,Sb,Se,Groups,compounds,which,are,charac,terized,ultralow,lattice,thermal,conductivity,because,their,strong,anharmonicity,caused,lone,pair,electrons,have,aroused,wide,attention,community,practical,application,devices,usually,requires,both,compatible,type,materials,simultaneously,However,most,intrinsic,semiconductors,lacking,counterparts,thermoelectrics,Herein,this,work,increase,alloying,order,stabilize,phase,room,temperature,With,further,optimization,electrical,could,improved,solid,solutions,Finally,nominal,composition,Br,show,maximum,zT,respectively
AB值:
0.553109
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