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典型文献
Recyclable Joule heated low shrinkage carbon nanofiber aerogels for microscale oil/water separation
文献摘要:
Aerogels have shown great potential as oil adsorbents but their application to the removal of microscale oil from water and their recycling remains problematic.The present work proposed a freeze-shaping method for fabricating carbon nanofiber aerogels(CNFAs)based on the direct use of one-dimensional(1D)carbon nanofibers(CNF)rather than carbonization of polymer aerogels.This technique greatly re-duces volume shrinkage and increases the three-dimensional(3D)structural stability of the material.Car-bon nanotubes(CNT)and gelatinized starch were incorporated in these aerogels as a conductive enhance-ment agent and binder,respectively,forming a"vine(CNT)-wrapped tree(CNF)"structure that improved mechanical and Joule-heating performance.The effects of glutaraldehyde added to aerogels as a cross-linking agent on mechanical properties and microstructure were also systematically investigated.The optimized CNFAs combined with low density,high porosity,good elasticity,and superior Joule-heating efficiency along with suitable adsorption capacity,excellent selectivity,and cycling stability.This mate-rial was able to selectively remove 87%and 92%of microscale acetone and dimethylformamide(DMF),respectively,from the water after nine cycles of adsorption and Joule-heating.The present work demon-strates a novel means of designing and fabricating a low shrinkage CNFA with outstanding Joule-heating performance having potential practical applications in the remediation of organic pollution.
文献关键词:
作者姓名:
Guangkai Hu;Dong Liu;Sidi Yin;Bin Yu;Tao Huang;Hao Yu;Meifang Zhu
作者机构:
State Key Laboratory for Modification of Chemical Fibers&Polymer Materials,College of Materials Science&Engineering,Donghua University,Shanghai 201620,China
引用格式:
[1]Guangkai Hu;Dong Liu;Sidi Yin;Bin Yu;Tao Huang;Hao Yu;Meifang Zhu-.Recyclable Joule heated low shrinkage carbon nanofiber aerogels for microscale oil/water separation)[J].材料科学技术(英文版),2022(32):89-97
A类:
CNFAs,gelatinized,CNFA
B类:
Recyclable,Joule,heated,low,shrinkage,aerogels,microscale,oil,water,separation,Aerogels,have,shown,potential,adsorbents,but,their,removal,from,recycling,remains,problematic,present,work,proposed,freeze,shaping,method,fabricating,direct,use,dimensional,1D,nanofibers,rather,than,carbonization,polymer,This,technique,greatly,duces,volume,increases,three,structural,stability,material,Car,nanotubes,CNT,starch,were,incorporated,these,conductive,enhance,ment,agent,binder,respectively,forming,vine,wrapped,tree,that,improved,mechanical,heating,performance,effects,glutaraldehyde,added,cross,linking,properties,microstructure,also,systematically,investigated,optimized,combined,density,high,porosity,good,elasticity,superior,efficiency,along,suitable,adsorption,capacity,excellent,selectivity,was,selectively,remove,acetone,dimethylformamide,DMF,after,nine,cycles,demon,strates,novel,means,designing,outstanding,having,practical,applications,remediation,organic,pollution
AB值:
0.578547
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