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典型文献
Efficient interfacial charge transfer of BiOCl-In2O3 step-scheme heterojunction for boosted photocatalytic degradation of ciprofloxacin
文献摘要:
BiOCl as a representative layered bismuth-based photocatalyst with Sillén-structure has aroused wide public concern on photocatalytic degradation.However,the photocatalytic efficiency of pristine BiOCl is currently restricted by its low optical absorption and charge separation efficiency.Herein,step-scheme(S-scheme)heterojunctions of In2O3 nanoparticle and BiOCl micron-sheet were constructed by a convenient molten salt method by using a LiNO3-KNO3 system.The In2O3-BiOCl heterojunctions exhibit higher opti-cal absorption performance from 380 nm to 700 nm than the pristine BiOCl and enhanced photocatalytic property toward ciprofloxacin(CIP)degradation under Xenon lamp illumination.The sample 20%In2O3-BiOCl showed the highest photodegradation efficiency,attaining 91%removal of CIP within 35 min,which was 39.6 times and 3.2 times higher than that of pristine In2O3 and BiOCl,respectively.The improved photodegradation property mainly resulted from the novel S-scheme mechanism,which boosted highly efficient separation of the photo-induced carriers.The photoluminescence spectrometric test and tran-sient photocurrent response results demonstrated that In2O3-BiOCl composite exhibited efficient separa-tion of photo-generated charge carriers.This work would provide new insights into the design of novel S-scheme photocatalytic systems with applicability in photocatalytic water treatment.
文献关键词:
作者姓名:
Kaiqiang Xu;Jie Shen;Shiying Zhang;Difa Xu;Xiaohua Chen
作者机构:
College of Materials Science and Engineering,Hunan University,Changsha 410082,China;Hunan Key Laboratory of Applied Environmental Photocatalysis,Changsha University,Changsha 410005,China
引用格式:
[1]Kaiqiang Xu;Jie Shen;Shiying Zhang;Difa Xu;Xiaohua Chen-.Efficient interfacial charge transfer of BiOCl-In2O3 step-scheme heterojunction for boosted photocatalytic degradation of ciprofloxacin)[J].材料科学技术(英文版),2022(26):236-244
A类:
Sill
B类:
Efficient,interfacial,charge,transfer,BiOCl,In2O3,step,scheme,boosted,photocatalytic,ciprofloxacin,representative,layered,bismuth,photocatalyst,structure,has,aroused,wide,public,concern,However,efficiency,pristine,currently,restricted,by,its,low,optical,absorption,separation,Herein,heterojunctions,nanoparticle,micron,sheet,were,constructed,convenient,molten,salt,method,using,LiNO3,KNO3,higher,performance,from,than,enhanced,property,toward,CIP,under,Xenon,lamp,illumination,sample,showed,highest,photodegradation,attaining,removal,within,which,was,times,that,respectively,improved,mainly,resulted,novel,mechanism,highly,efficient,induced,carriers,photoluminescence,spectrometric,test,sient,photocurrent,response,results,demonstrated,composite,exhibited,generated,This,work,would,provide,new,insights,into,design,systems,applicability,water,treatment
AB值:
0.543443
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