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典型文献
Strong interface contact between NaYF4∶Yb,Er and CdS promoting photocatalytic hydrogen evolution of NaYF4∶Yb,Er/CdS composites
文献摘要:
To acquire efficient photocatalysts,it is necessary to make effective use of visible light/Near Infrared(NIR)light,which takes up a large percentage of sunlight.Integrating upconversion materials with visible light active photocatalysts has attracted much attention in this regard.The interface contact between upcon-version material and photocatalyst has potential influence on the properties and thus the performance of the system.In this work,NaYF4∶Yb,Er/CdS composites of the upconversion material NaYF4∶Yb,Er nanorods and CdS nanoparticles were synthesized by ion adsorption/precipitation process and were then annealed in an argon atmosphere at different temperatures to modulate the microstructures.The annealing pro-cess endows the crystal transformation of cubic CdS with low crystallinity to hexagonal CdS with high crystallinity and,importantly,good interface contact between NaYF4∶Yb,Er and CdS.Consequently,the hy-drogen evolution activity greatly increases from 171 to 2539 μmol h-1 g-1 under the light irradiation ofλ>400 nm,and from 0 to 19 μmol h-1 g-1 under the light irradiation of λ>600 nm.This work might provide a useful reference for the rational design of promising photocatalyst involving upconversion ma-terials.
文献关键词:
作者姓名:
Huaze Zhu;Yongqiang Yang;Yuyang Kang;Ping Niu;Xiangdong Kang;Zhiqing Yang;Hengqiang Ye;Gang Liu
作者机构:
Shenyang National Laboratory for Materials Science,Institute of Metal Research,Chinese Academy of Sciences,Shenyang 110016,China;School of Materials Science and Engineering,University of Science and Technology of China,Shenyang 110016,China;School of Metallurgy,Northeastern University,Shenyang 110819,China;Jihua Laboratory,Foshan 528000,China
引用格式:
[1]Huaze Zhu;Yongqiang Yang;Yuyang Kang;Ping Niu;Xiangdong Kang;Zhiqing Yang;Hengqiang Ye;Gang Liu-.Strong interface contact between NaYF4∶Yb,Er and CdS promoting photocatalytic hydrogen evolution of NaYF4∶Yb,Er/CdS composites)[J].材料科学技术(英文版),2022(07):1-7
A类:
upcon
B类:
Strong,interface,contact,between,NaYF4,Yb,Er,CdS,promoting,photocatalytic,hydrogen,evolution,composites,To,acquire,efficient,photocatalysts,necessary,make,effective,visible,Near,Infrared,NIR,which,takes,large,percentage,sunlight,Integrating,upconversion,materials,active,has,attracted,much,attention,this,regard,potential,influence,properties,thus,performance,system,work,nanorods,nanoparticles,were,synthesized,by,adsorption,precipitation,process,then,annealed,argon,atmosphere,different,temperatures,modulate,microstructures,annealing,endows,transformation,cubic,low,crystallinity,hexagonal,high,importantly,good,Consequently,activity,greatly,increases,from,under,irradiation,This,might,provide,useful,reference,rational,design,promising,involving
AB值:
0.50226
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