典型文献
Na2O/Li2O Ratio Dependency on the Thermal, Mechanical, Dielectric Properties and Chemical Stabilities of Li2O-Al2O3-SiO2 Glass
文献摘要:
Li2O-Al2O3-SiO2 based glasses were investigated as potential protection glass for electronic devices due to their excellent mechanical properties, such as high hardness, toughness, and scratch resistance. In this paper, Li2O-Na2O-Al2O3-SiO2 glass with different Li2O/Na2O ratio components were prepared by melt-quenching method, and the effects of Na2O/Li2O ratio on the glass densities, structure, thermal, mechanical properties, and chemical stabilities were studied. The experimental results indicate that the glass transition temperature increases with the increases in Na2O/Li2O ratios, due to larger ion radius. While the thermal expansion coefficient slightly decreases from 11.4 × 10-6 to 11.09 × 10-6 /℃. The elastic modulus increases from 57 to 72 GPa. The bending strength reaches maximum 80.90 MPa when the Na2O/Li2O ratio is 1.7, then decreases as the ratio further increases. In addition, the Vicker's hardness gets to 7.37 GPa with largest Na2O/Li2O ratio. Moreover, the dielectric loss and dielectric constant increases as the ratio increases. The Raman structure analysis shows the Q4 [Si-O-Si] decreases as Na2O/Li2O ratio increases, which is responsible for the characteristic properties change. Moreover, the glass shows lowest mass loss in 10vol% HF solutions when the ratio is 1.4, while 1.7 in 5wt% NaOH solution.
文献关键词:
中图分类号:
作者姓名:
CHEN Lina;XIE Jun;WANG Mingzhong;CAO Shiyi;CUI Xiuzhen;LIANG Xinhui;ZHANG Jihong;HAN Jianjun;HU Kaiwen
作者机构:
State Key Laboratory of Silicate Materials for Architectures,Wuhan University of Technology,Wuhan 430070,China;Shenzhen Re-search Institute of Wuhan University of Technology,Shenzhen 518000,China;Xianning Nanbo Photoelectric Glass Co.Ltd.,Xianning 437100,China;International School of Materials Science and Engineering,Wuhan University of Technology,Wuhan 430070,China
文献出处:
引用格式:
[1]CHEN Lina;XIE Jun;WANG Mingzhong;CAO Shiyi;CUI Xiuzhen;LIANG Xinhui;ZHANG Jihong;HAN Jianjun;HU Kaiwen-.Na2O/Li2O Ratio Dependency on the Thermal, Mechanical, Dielectric Properties and Chemical Stabilities of Li2O-Al2O3-SiO2 Glass)[J].武汉理工大学学报(材料科学版)(英文版),2022(06):1129-1136
A类:
Vicker,10vol
B类:
Na2O,Li2O,Ratio,Dependency,Thermal,Mechanical,Dielectric,Properties,Chemical,Stabilities,Al2O3,SiO2,Glass,glasses,were,investigated,potential,protection,electronic,devices,due,their,excellent,mechanical,properties,such,high,hardness,toughness,scratch,resistance,In,this,paper,different,components,prepared,by,melt,quenching,method,effects,densities,structure,thermal,chemical,stabilities,studied,experimental,results,indicate,that,transition,temperature,increases,ratios,larger,radius,While,expansion,coefficient,slightly,decreases,from,elastic,modulus,GPa,bending,strength,reaches,maximum,when,then,further,addition,gets,largest,Moreover,dielectric,loss,constant,Raman,analysis,shows,Q4,which,responsible,characteristic,change,lowest,mass,HF,solutions,while,5wt,NaOH
AB值:
0.510642
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