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典型文献
Facet Regulation of Fe2O3 via Nanoarray Architecture to Enable High Faradic Efficiency for Electrocatalytic Nitrogen Fixation
文献摘要:
We propose a facile facet regulation enabled by nanoarray architecture to achieve a high faradic efficiency of Fe2O3 catalyst for NRR.The a-Fe2O3 nanorod arrays(NAs)were directly grown on carbon cloth(CC)with specific(104)facet exposure.The highly exposed(104)facets provide abundant unsaturated Fe atoms with dangling bonds as nitrogen reduction reaction catalytically active sites.In addition,the NAs architecture enables the enhanced electrochemical surface area(ECSA)to fully manifest the active sites and maintain the mass diffusion.Thus,the selectively exposed(104)facets coupled with the high ECSA of NAs architecture achieve a high FE of 14.89%and a high yield rate of 17.28 pg h-1 cm-2.This work presents an effective strategy to develop highly efficient catalytic electrodes for electrochemical NRR via facet regulation and nanoarray architecture.
文献关键词:
作者姓名:
XIE Anqi;XIAO Liang;QIAO Qiumin;LIU Jinping
作者机构:
School of Chemistry,Chemical Engineering and Life Science,Wuhan University of Technology,Wuhan 430070,China;State Key Lab-oratory of Advanced Technology for Materials Synthesis and Processing,Wuhan University of Technology,Wuhan 430070,China
引用格式:
[1]XIE Anqi;XIAO Liang;QIAO Qiumin;LIU Jinping-.Facet Regulation of Fe2O3 via Nanoarray Architecture to Enable High Faradic Efficiency for Electrocatalytic Nitrogen Fixation)[J].武汉理工大学学报(材料科学版)(英文版),2022(05):807-814
A类:
Nanoarray,faradic
B类:
Facet,Regulation,Fe2O3,via,Architecture,Enable,High,Faradic,Efficiency,Electrocatalytic,Nitrogen,Fixation,We,propose,facile,regulation,enabled,by,nanoarray,architecture,achieve,efficiency,catalyst,NRR,nanorod,arrays,NAs,were,directly,grown,carbon,cloth,CC,specific,exposure,highly,exposed,facets,provide,abundant,unsaturated,atoms,dangling,bonds,nitrogen,reduction,reaction,catalytically,active,sites,In,addition,enables,enhanced,electrochemical,surface,area,ECSA,fully,manifest,maintain,mass,diffusion,Thus,selectively,coupled,FE,yield,pg,This,work,presents,effective,strategy,develop,efficient,electrodes
AB值:
0.630603
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