首站-论文投稿智能助手
典型文献
Hydrothermal-treated Pt/Al2O3 as an excellent catalyst for toluene total oxidation
文献摘要:
The preparation of highly active supported noble metal catalysts with a low noble metal loading has always been the ultimate goal of researchers working on catalysis.Hydrother-mally treated Pt/Al2O3(Pt/Al2O3-H)exhibits better catalytic activity than that(Pt/Al2O3-C)treated via the conventional calcination approach.At the high space velocity of 100,000 mL/(g·hr),the temperature that correspond to 50%toluene conversion(T50)of Pt/Al2O3-H is 115℃lower than that of Pt/Al2O3-C,and the turnover frequency(TOF)value can reach 0.0756 sec-1.The mechanism by which the hydrothermal approach enhances Pt/Al2O3 activity has been investigated.The structure associated with the high catalytic ac-tivity of Pt nanoparticles(NPs)can be retained via hydrothermal treatment.Furthermore,the support is transformed to AlO(OH)with numerous surface hydroxyl groups,which in turn can facilitate the adsorption of toluene.And the synergistic effects of Pt NPs and AlO(OH)increases the contents of Pt in oxidation state and active oxygen,which are bene-ficial for toluene oxidation.
文献关键词:
作者姓名:
Xiao Chen;Yong Wang;Jianyu Li;Zhongheng Hu;Ying Zhou;Huayan Liu;Hanfeng Lu
作者机构:
Institute of Catalytic Reaction Engineering,College of Chemical Engineering,Zhejiang University of Technology,Hangzhou 310014,China
引用格式:
[1]Xiao Chen;Yong Wang;Jianyu Li;Zhongheng Hu;Ying Zhou;Huayan Liu;Hanfeng Lu-.Hydrothermal-treated Pt/Al2O3 as an excellent catalyst for toluene total oxidation)[J].环境科学学报(英文版),2022(06):114-124
A类:
Hydrother
B类:
Hydrothermal,treated,Pt,Al2O3,excellent,toluene,total,oxidation,preparation,highly,active,supported,noble,metal,catalysts,loading,has,always,been,ultimate,goal,researchers,working,catalysis,mally,exhibits,better,catalytic,activity,than,that,via,conventional,calcination,approach,At,space,velocity,hr,temperature,correspond,conversion,T50,lower,turnover,frequency,TOF,value,can,reach,sec,mechanism,by,which,hydrothermal,enhances,investigated,structure,associated,nanoparticles,NPs,retained,treatment,Furthermore,transformed,AlO,numerous,surface,hydroxyl,groups,facilitate,adsorption,And,synergistic,effects,increases,contents,state,oxygen,are,bene,ficial
AB值:
0.546684
相似文献
Interface engineering of snow-like Ru/RuO2 nanosheets for boosting hydrogen electrocatalysis
Juntao Zhang;Guomian Ren;Deyu Li;Qingyu Kong;Zhiwei Hu;Yong Xu;Suling Wang;Lu Wang;Maofeng Cao;Xiaoqing Huang-State Key Laboratory of Physical Chemistry of Solid Surfaces,College of Chemistry and Chemical Engineering,Xiamen University,Xiamen 361005,China;Guangzhou Key Laboratory of Low-Dimensional Materials and Energy Storage Devices,Collaborative Innovation Center of Advanced Energy Materials,School of Materials and Energy,Guangdong University of Technology,Guangzhou 510006,China;Institute of Functional Nano&Soft Materials,Jiangsu Key Laboratory for Carbon-Based Functional Materials&Devices,Soochow University,Suzhou 215123,China;Société Civile Synchrotron SOLEIL,L'Orme des Merisiers,Saint-Aubin 91192,France;School of Physics Science and Information Engineering,Shandong Key Laboratory of Optical Communication Science and Technology,Liaocheng University,Liaocheng 252059,China;Max Planck Institute for Chemical Physics of Solids,Dresden 01187,Germany
Engineering the morphology and electronic structure of atomic cobalt-nitrogen-carbon catalyst with highly accessible active sites for enhanced oxygen reduction
Zhijun Li;Leipeng Leng;Siqi Ji;Mingyang Zhang;Hongxue Liu;Jincheng Gao;Jiangwei Zhang;J.Hugh Horton;Qian Xu;Junfa Zhu-Joint International Research Laboratory of Advanced Chemical Catalytic Materials&Surface Science,College of Chemistry and Chemical Engineering,Northeast Petroleum University,Daqing 163318,Heilongjiang,China;Dalian National Laboratory for Clean Energy&State Key Laboratory of Catalysis,Dalian Institute of Chemical Physics,Chinese Academy of Sciences,Dalian 116023,Liaoning,China;Department of Chemistry,Queen's University,Kingston,Ontario K7L 3N6,Canada;National Synchrotron Radiation Laboratory,University of Science and Technology of China,Hefei 230029,Anhui,China
机标中图分类号,由域田数据科技根据网络公开资料自动分析生成,仅供学习研究参考。