典型文献
Optical and electrical conductivity properties of rare earth elements(Sm,Y,La,Er)co-doped CeO2
文献摘要:
In this research,un-doped CeO2 and Ce0.85La0.10M0.05O2(M∶Sm,Er,Y)compounds were synthesized by hydrothermal method and the multi-functional properties are reported.Oxygen defects were created with the additives of rare earth ions.The electrical and luminescence behaviors of the synthesized compounds were investigated in accord with the types of additives.The synthesized products were characterized by X-ray diffraction(XRD)analysis,Brunauer-Emmett-Teller(BET)measurement,UV-vis diffuse reflectance spectroscopy(DRS),scanning electron microscopy(SEM),photoluminescence(PL)spectroscopy and electrochemical impedance spectroscopic(EIS).All synthesized compounds are found to be nano-structured and have cubic phase.The total conductivity of all samples was calculated.Hence,the total conductivity of un-doped CeO2,Ce0.85La0.10Y0.05O2,Ce0.85La0.10Er0.05O2 and Ce0.85La0.10Sm0.05O2 is found to be 2.07×10-10,5.70×10-4,1.0×10-3 and 0.0747 S/cm,respectively.Also,bandgap energy(Eg)of these samples calculated from UV visible absorption spectra is discussed,and the optical results show variation between 3.2 and 2.15 eV.Additionally,the luminescence properties of the compounds were investigated and different emissions occur depending on the additive type.Accordingly,photo-luminescent emission spectra of Ce0.85La0.10Y0.05O2,Ce0.85La0.10Er0.05O2 and Ce0.85La0.10Sm0.05O2 phos-phors indicate that these phosphors have red,green and orange-red colors,respectively.
文献关键词:
中图分类号:
作者姓名:
Rabia K(i)rkge?it;Handan ?zlü Torun;Fatma K(i)l(i)? Dokan;Esra ?ztürk
作者机构:
Institute of Science,Material Science and Engineering,Kahramanmara? Süt?ü(I)mam University,Kahramanmara?,46050,Turkey;Department of Energy System Engineering,Kahramanmara?(I)stiklal University,Kahramanmara?,46300,Turkey;Department of Chemistry and Chemical Processing Technologies,Kayseri University,Kayseri,Turkey;Department of Metallurgical and Materials Engineering,Karamanoglu Mehmetbey University,Karaman,Turkey
文献出处:
引用格式:
[1]Rabia K(i)rkge?it;Handan ?zlü Torun;Fatma K(i)l(i)? Dokan;Esra ?ztürk-.Optical and electrical conductivity properties of rare earth elements(Sm,Y,La,Er)co-doped CeO2)[J].稀土学报(英文版),2022(10):1619-1627
A类:
85La0,10M0,10Y0,10Er0,10Sm0,phors
B类:
Optical,electrical,conductivity,properties,rare,earth,elements,doped,CeO2,In,this,research,Ce0,05O2,compounds,were,synthesized,by,hydrothermal,method,multi,functional,reported,Oxygen,defects,created,additives,behaviors,investigated,accord,types,products,characterized,ray,diffraction,analysis,Brunauer,Emmett,Teller,BET,measurement,UV,diffuse,reflectance,spectroscopy,DRS,scanning,electron,microscopy,photoluminescence,PL,electrochemical,impedance,spectroscopic,EIS,All,found,nano,structured,have,cubic,phase,total,samples,was,calculated,Hence,respectively,Also,bandgap,energy,Eg,these,from,visible,absorption,spectra,discussed,optical,results,show,variation,between,eV,Additionally,different,emissions,occur,depending,Accordingly,luminescent,indicate,that,phosphors,green,orange,colors
AB值:
0.438409
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