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典型文献
Synergistic effects of CeO2/Cu2O on CO catalytic oxidation:Electronic interaction and oxygen defect
文献摘要:
For CO catalytic oxidation,Cu and Ce species are of great importance,between which the synergistic effect is worth investigating.In this work,CeO2/Cu2O with Cu2O{111}and{100}planes were compar-atively explored on CO catalytic oxidation to reveal the effects of interfacial electronic interactions and oxygen defects.The activity result demonstrates that CeO2/o-Cu2O{111}has superior performance compared with CeO2/c-Cu2O{100}.Credit to the coordination unsaturated copper atoms(Cucus)on o-Cu2O{111}surface,the interfacial electronic interactions on CeO2/o-Cu2O{111}are more obvious than those on CeO2/c-Cu2O{100},leading to richer oxygen defect generation,better redox and activation abilities of CO and O2 reactants.Furthermore,the reaction mechanism of CeO2/o-Cu2O{111}on CO oxidation is revealed,i.e.,CO and O2 are adsorbed on the Cucus on Cu2O{111}and oxygen defect of CeO2,respectively,and then synergistically promote the CO oxidation to CO2.The work sheds light on the designing optimized ceria and copper-based catalysts and the mechanism of CO oxidation.
文献关键词:
作者姓名:
Chengyan Ge;Jingfang Sun;Qing Tong;Weixin Zou;Lulu Li;Lin Dong
作者机构:
School of Chemistry and Chemical Engineering,Yancheng Institute of Technology,Yancheng 224051,China;Jiangsu Key Laboratory of Vehicle Emissions Control,Center of Modern Analysis,School of the Environment,Nanjing University,Nanjing 210093,China;School of Environmental and Chemical Engineering,Jiangsu University of Science and Technology,Zhenjiang 212003,China
引用格式:
[1]Chengyan Ge;Jingfang Sun;Qing Tong;Weixin Zou;Lulu Li;Lin Dong-.Synergistic effects of CeO2/Cu2O on CO catalytic oxidation:Electronic interaction and oxygen defect)[J].稀土学报(英文版),2022(08):1211-1218
A类:
Cucus
B类:
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AB值:
0.461708
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