典型文献
Construction of chiral 3-alkenyl-3-substituted oxindoles by stereoselective direct alkenylation of isatin derivatives and 3-vinylindoles
文献摘要:
An efficient asymmetric alkenylation between 3-vinylindoles and isatin derivatives was developed under catalysis of a chiral copper complex.A series of optically active 3-alkenyl-3-substituted oxindoles were obtained in excellent yields and stereoselectivities.The reaction mechanism was proposed and supported by DFT calculation.
文献关键词:
中图分类号:
作者姓名:
Xiang Sun;Kuiliang Li;Shuangshuang Zhao;Zhenggen Zha;Zhiyong Wang
作者机构:
Hefei National Research Center for Physical Sciences at the Microscale,Center for Excellence in Molecular Synthesis of Chinese Academy of Sciences,School of Chemistry and Materials Science,University of Science and Technology of China,Hefei 230026,China
文献出处:
引用格式:
[1]Xiang Sun;Kuiliang Li;Shuangshuang Zhao;Zhenggen Zha;Zhiyong Wang-.Construction of chiral 3-alkenyl-3-substituted oxindoles by stereoselective direct alkenylation of isatin derivatives and 3-vinylindoles)[J].中国化学快报(英文版),2022(12):5106-5110
A类:
oxindoles,alkenylation,isatin,vinylindoles,stereoselectivities
B类:
Construction,chiral,substituted,by,stereoselective,direct,derivatives,An,efficient,asymmetric,between,was,developed,under,catalysis,copper,complex,series,optically,active,were,obtained,excellent,yields,reaction,mechanism,proposed,supported,DFT,calculation
AB值:
0.487132
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