典型文献
Boron-promoted reductive deoxygenation coupling reaction of sulfonyl chlorides for the C(sp3)-S bond construction
文献摘要：
Herein,we report a borane-promoted reductive deoxygenation coupling reaction to synthesize sulfides.This reaction features excellent functional group compatibility,high efficiency,broad substrate scope,and application in late-stage functionalization of biomolecules.Preliminary mechanistic studies suggest di-aryl sulfides are the intermediates of this reaction.Moreover,the real active aryl sulfide anions may be generated in situ with the aid of B2pin2 and react with alkyl tosylates through a concerted SN2 pathway.
文献关键词：
中图分类号：
作者姓名：
Shuo Chen;Qingru Wen;Yanqing Zhu;Yanru Ji;Yu Pu;Zhengli Liu;Yun He;Zhang Feng
作者机构：
Chongqing Key Laboratory of Natural Product Synthesis and Drug Research,School of Pharmaceutical Sciences,Chongqing University,Chongqing 401331,China;Medical Imaging Key Laboratory of Sichuan Province,North Sichuan Medical College,Nanchong 637000,China
文献出处：
引用格式：
[1]Shuo Chen;Qingru Wen;Yanqing Zhu;Yanru Ji;Yu Pu;Zhengli Liu;Yun He;Zhang Feng-.Boron-promoted reductive deoxygenation coupling reaction of sulfonyl chlorides for the C(sp3)-S bond construction)[J].中国化学快报（英文版）,2022(12):5101-5105
A类：
B2pin2,tosylates
B类：
Boron,promoted,reductive,deoxygenation,coupling,reaction,sulfonyl,chlorides,sp3,bond,construction,Herein,we,report,borane,synthesize,sulfides,This,features,excellent,group,compatibility,high,efficiency,broad,substrate,scope,application,stage,functionalization,biomolecules,Preliminary,mechanistic,studies,suggest,aryl,are,intermediates,this,Moreover,real,active,anions,may,be,generated,situ,aid,alkyl,through,concerted,SN2,pathway
AB值：
0.685584
相似文献
机标中图分类号，由域田数据科技根据网络公开资料自动分析生成，仅供学习研究参考。
