典型文献
Integrating aryl chlorides into nickel-catalyzed 1,1-difunctionalization of alkenes
文献摘要：
Difunctionalization of alkenes have developed into an important type of reactions for rapidly and effi-ciently assemble complex molecules.While extensive advancements have been achieved by the assis-tance of transition metal catalysis,the employment of cheap,abundant aryl chlorides as coupling partner is still a challenging task in this field.Herein,we report our first achievement in 1,1-difunctionalization of alkenes with aryl chlorides as coupling partners.The success is predominantly ascribed to the judicious selection of 1,2-diamine ligand.This study provides an efficient protocol for the synthesis of secondary benzyl boronates from easily accessible feedstock chemicals.Furthermore,the distinguished features of this method include excellent 1,1-regio-and chemoselectivity,good functional group tolerance and easily-operational catalytic reaction conditions.
文献关键词：
中图分类号：
作者姓名：
Caocao Sun;Guoyin Yin
作者机构：
The Institute for Advanced Studies,Wuhan University,Wuhan 430072,China
文献出处：
引用格式：
[1]Caocao Sun;Guoyin Yin-.Integrating aryl chlorides into nickel-catalyzed 1,1-difunctionalization of alkenes)[J].中国化学快报（英文版）,2022(12):5096-5100
A类：
difunctionalization,Difunctionalization,assis,boronates
B类：
Integrating,aryl,chlorides,into,nickel,catalyzed,alkenes,have,developed,important,type,reactions,rapidly,ciently,assemble,complex,molecules,While,extensive,advancements,been,achieved,by,tance,transition,metal,catalysis,employment,cheap,abundant,coupling,still,challenging,task,this,field,Herein,we,report,our,first,achievement,partners,success,predominantly,ascribed,judicious,selection,diamine,ligand,This,study,provides,efficient,protocol,synthesis,secondary,benzyl,from,easily,accessible,feedstock,chemicals,Furthermore,distinguished,features,method,include,excellent,regio,chemoselectivity,good,group,tolerance,operational,catalytic,conditions
AB值：
0.658719
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