典型文献
In situ conversion builds MIL-101@NiFe-LDH heterojunction structures to enhance the oxygen evolution reaction
文献摘要:
The construction of rich phase interfaces to increase active reaction area in hybrid materials is an excel-lent strategy to improve electrochemical performance.Under this guideline,MIL-101@OX-metal organic framework(MOF)is constructed by the"MOF on MOF"method,then converts to MIL-101@NiFe-layered double hydroxides(LDH)by in situ transformation in alkaline solution.MIL-101@NiFe-LDH shows ex-cellent electrochemical water oxidation performance.It needs only an overpotential of 215 mV to drive 10 mA/cm2 of oxygen evolution reaction(OER),which is less than that of NiFe-LDH,MIL-101.In addition,MIL-101@NiFe-LDH has the smallest Tafel slope(55.1 mV/dec)compared with NiFe-LDH(61.1 mV/dec),MIL-101(150.8 mV/dec).The excellent water oxidation activity is due to the high phase interfaces de-rived from high specific surface area of MOF.This work offers an alternative method for making MOF/LDH heterostructures with an optimized phase interfaces and provides new insights for OER.
文献关键词:
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作者姓名:
Jingwei Huang;Kai Li;Lei Wang;Houde She;Qizhao Wang
作者机构:
College of Chemistry and Chemical Engineering,Gansu International Scientific and Technological Cooperation Base of Water-Retention Chemical Functional Materials,Northwest Normal University,Lanzhou 730070,China;School of Environmental Science and Engineering,Chang'an University,Xi'an 710054,China;Tianjin Key Laboratory of Building Green Functional Materials,Tianjin Chengjian University,Tianjin 300384,China
文献出处:
引用格式:
[1]Jingwei Huang;Kai Li;Lei Wang;Houde She;Qizhao Wang-.In situ conversion builds MIL-101@NiFe-LDH heterojunction structures to enhance the oxygen evolution reaction)[J].中国化学快报(英文版),2022(08):3787-3791
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In,situ,conversion,builds,MIL,NiFe,LDH,heterojunction,enhance,oxygen,evolution,reaction,construction,rich,phase,interfaces,increase,active,area,hybrid,materials,strategy,improve,electrochemical,performance,Under,this,guideline,OX,metal,organic,framework,MOF,constructed,by,method,then,converts,layered,double,hydroxides,transformation,alkaline,solution,shows,water,oxidation,It,needs,only,overpotential,mV,drive,mA,OER,which,less,than,that,addition,smallest,Tafel,slope,dec,compared,excellent,activity,due,high,rived,from,specific,surface,This,offers,alternative,making,heterostructures,optimized,provides,new,insights
AB值:
0.528962
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