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典型文献
Scalable synthesis of Na3V2(PO4)3/C with high safety and ultrahigh-rate performance for sodium-ion batteries
文献摘要:
NASICON-type Na3V2(PO4)3 is a promising electrode material for developing advanced sodium-ion bat-teries.Preparing Na3V2(PO4)3 with good performance by a cost-effective and large-scale method is signif-icant for industrial applications.In this work,a porous Na3V2(PO4)3/C cathode material with excellent electrochemical performance is successfully prepared by an agar-gel combined with freeze-drying method.The Na3V2(PO4)3/C cathode displayed specific capacities of 113.4 mAh·g-1,107.0 mAh·g-1 and 87.1 mAh·g-1 at 0.1 C,1 C and 10C,respectively.For the first time,the 500-mAh soft-packed symmetrical sodium-ion batteries based on Na3V2(PO4)3/C electrodes are successfully fabricated.The 500-mAh sym-metrical batteries exhibit outstanding low temperature performance with a capacity retention of 83%at 0℃owing to the rapid sodium ion migration ability and structural stability of Na3V2(PO4)3/C.Moreover,the thermal runaway features are revealed by accelerating rate calorimetry(ARC)test for the first time.Thermal stability and safety of the symmetrical batteries are demonstrated to be better than lithium-ion batteries and some reported sodium-ion batteries.Our work makes it clear that the soft-packed symmet-rical sodium ion batteries based on Na3V2(PO4)3/C have a prospect of practical application in high safety requirement fields.
文献关键词:
作者姓名:
Guijia Cui;Hong Wang;Fengping Yu;Haiying Che;Xiaozhen Liao;Linsen Li;Weimin Yang;Zifeng Ma
作者机构:
Department of Chemical Engineering,Shanghai Electrochemical Energy Devices Research Center,Shanghai Jiao Tong University,Shanghai 200240,China;SINOPEC Shanghai Research Institute of Petrochemical Technology,Shanghai 201208,China;Zhejiang NaTRIUM Energy Co.Ltd.,Shaoxing 312000,China
引用格式:
[1]Guijia Cui;Hong Wang;Fengping Yu;Haiying Che;Xiaozhen Liao;Linsen Li;Weimin Yang;Zifeng Ma-.Scalable synthesis of Na3V2(PO4)3/C with high safety and ultrahigh-rate performance for sodium-ion batteries)[J].中国化学工程学报(英文版),2022(06):280-286
A类:
metrical
B类:
Scalable,synthesis,Na3V2,PO4,safety,ultrahigh,performance,sodium,batteries,NASICON,type,promising,material,developing,advanced,Preparing,good,by,cost,effective,large,scale,method,signif,icant,industrial,applications,In,this,work,porous,cathode,excellent,electrochemical,successfully,prepared,agar,gel,combined,freeze,drying,displayed,specific,capacities,mAh,10C,respectively,For,first,soft,packed,symmetrical,electrodes,fabricated,exhibit,outstanding,low,temperature,capacity,retention,owing,rapid,migration,structural,stability,Moreover,thermal,runaway,features,revealed,accelerating,calorimetry,ARC,test,Thermal,demonstrated,better,than,lithium,some,reported,Our,makes,clear,that,have,prospect,practical,requirement,fields
AB值:
0.48118
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