典型文献
Regulatable pervaporation performance of Zn-MOFs/polydimethylsiloxane mixed matrix pervaporation membranes
文献摘要：
Pervaporation(PV)is an emerging separation technique for liquid mixture.Mixed matrix membranes(MMMs)often demonstrate trade-off relationship between separation factor and flux.In this study,by changing the organic linkers(2-methyl imidazolate,imidazole-2-carboxaldehyde,2-ethyl imidazolate),ZIF-8,ZIF-90 and MAF-6 were prepared and filled in polydimethylsiloxane(PDMS)membranes for deal-coholization of 5％(mass)n-butanol solution,and the membranes properties and pervaporation perfor-mances were adjusted.Compared with the pure PDMS membrane,the addition of ZIF-8 resulted in a 9％increase in flux(1136 g·m-2·h-1)and a 22.5％increase in separation factor(28.3),displaying anti-trade-off effect.For the MAF-6/PDMS MMMs(2.0％mass loading),the pervaporation separation index(PSI)and separation factor were 32347 g·m-2·h-1 and 58.6 respectively(increased by 34％and 154％in contrast with that of the pure PDMS membrane),and the corresponding permeation flux was 552 g·m-2·h-1,presenting great potential in the removal butanol from water.It was deduced that the large aperture size combined with moderate hydrophobicity of metal-organic frameworks(MOFs)favor the concurrent increase in permeability and selectivity.
文献关键词：
中图分类号：
作者姓名：
Guorong Wu;Qiangwen Fan;Wenjie Sun;Zhiwu Yu;Zhiqian Jia;Jianguo Ma
作者机构：
Jiangxi Province Key Laboratory of Polymer Micro/Nano Manufacturing and Devices,East China University of Technology,Nanchang 330013,China;Foshan(Southern China)Institute for New Materials,Foshan 528247,China;State Key Laboratory of Nuclear Resources and Environment,School of Biology,Chemistry and Material Science,East China University of Technology,Nanchang,330013,China;Jiangxi Province Key Laboratory of Synthetic Chemistry,School of Chemistry,Biology and Material Science,East China University of Technology,Nanchang 330013,China;Lab for Membrane Science and Technology,College of Chemistry,Beijing Normal University,Beijing 100875,China
文献出处：
引用格式：
[1]Guorong Wu;Qiangwen Fan;Wenjie Sun;Zhiwu Yu;Zhiqian Jia;Jianguo Ma-.Regulatable pervaporation performance of Zn-MOFs/polydimethylsiloxane mixed matrix pervaporation membranes)[J].中国化学工程学报（英文版）,2022(02):312-318
A类：
Regulatable,coholization
B类：
pervaporation,performance,MOFs,polydimethylsiloxane,mixed,matrix,membranes,Pervaporation,PV,emerging,separation,technique,liquid,mixture,Mixed,MMMs,often,demonstrate,trade,off,relationship,between,flux,In,this,study,by,changing,organic,linkers,imidazolate,imidazole,carboxaldehyde,ZIF,MAF,were,prepared,filled,PDMS,deal,mass,butanol,solution,properties,mances,adjusted,Compared,pure,addition,resulted,displaying,anti,effect,For,loading,PSI,respectively,increased,contrast,that,corresponding,permeation,was,presenting,great,potential,removal,from,water,It,deduced,large,aperture,size,combined,moderate,hydrophobicity,metal,frameworks,favor,concurrent,permeability,selectivity
AB值：
0.546179
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