典型文献
Improving hydrocarbons production via catalytic co-pyrolysis of torrefied-biomass with plastics and dual catalytic pyrolysis
文献摘要:
To increase the low yield and selectivity of aromatic hydrocarbons during the biomass pyrolysis process,we torrefied the biomass and then co-pyrolyzing with plastics such as high-density polyethylene(HDPE),polystyrene(PS),ethylene-vinyl acetate(EVA)and polypropylene(PP)and also single and dual catalyst layouts were investigated by Py-GC/MS.The results showed that non-catalytic fast pyrolysis(CFP)of raw bagasse(RBG)generated no aromatics.After torrefaction non-CFP of torrefied bagasse(TBG)generated low aromatic yield.Indicating that torrefaction would enhance the proportion of aromatics during the pyrolysis process.The CFP of TBG200℃and TBG240℃over ZSM-5 produced the total aromatic yield of 1.96 and 1.88 times higher,respectively,compared to non-CFP of TBG.Furthermore,the addition of plas-tic could increase H/Ceff ratio of the mixture,consequently,increase the yield of aromatic compounds.Among the various torrefied-bagasse/plastic mixtures,the CFP of TBG/EVA(7∶3 ratio)mixture generated the highest the total aromatic yield of 7.7 times more than the CFP of TBG alone.The dual catalyst layout could enhance the yield of aromatics hydrocarbons.The dual-catalytic co-pyrolysis of TBG200℃/plastic(1∶1)ratio over USY(ultra-stable Y zeolite)/ZSM-5,improved the total aromatics yield by 4.33 times more than the catalytic pyrolysis of TBG200℃alone over ZSM-5 catalyst.The above results showed that the yield and selectivities of light aromatic hydrocarbons can be improved via catalytic co-pyrolysis and dual catalytic co-pyrolysis of torrefied-biomass with plastics.
文献关键词:
中图分类号:
作者姓名:
Peter Keliona Wani Likun;Huiyan Zhang;Yuyang Fan
作者机构:
Key Laboratory of Thermal Energy Conversion and Control Ministry of Education,Southeast University,Nanjing 210096,China;Department of Mechanical Engineering,Juba University,Juba,P.O.Box 82,South Sudan
文献出处:
引用格式:
[1]Peter Keliona Wani Likun;Huiyan Zhang;Yuyang Fan-.Improving hydrocarbons production via catalytic co-pyrolysis of torrefied-biomass with plastics and dual catalytic pyrolysis)[J].中国化学工程学报(英文版),2022(02):196-209
A类:
torrefied,torrefaction,Indicating,TBG200,TBG240
B类:
Improving,hydrocarbons,production,via,catalytic,pyrolysis,biomass,plastics,dual,To,increase,low,yield,selectivity,during,process,then,pyrolyzing,such,density,polyethylene,HDPE,polystyrene,PS,vinyl,acetate,EVA,polypropylene,PP,also,single,catalyst,layouts,were,investigated,by,Py,results,showed,that,fast,CFP,raw,bagasse,RBG,generated,aromatics,After,would,enhance,proportion,over,ZSM,produced,total,times,higher,respectively,compared,Furthermore,addition,could,Ceff,ratio,consequently,compounds,Among,various,mixtures,highest,than,alone,USY,ultra,stable,zeolite,improved,above,selectivities,light,can,be
AB值:
0.342195
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