典型文献
Hydrogen peroxide and applications in green hydrocarbon nitridation and oxidation
文献摘要：
Basic organic chemicals and high value-added products are mainly produced by hydrocarbon nitridation and oxidation.However,several drawbacks limit the application of the traditional oxidation and nitrida-tion technologies in the future,such as complex processes,poor intrinsic safety,low atom utilization,and serious environmental pollution.The green nitridation and oxidation technologies are urgently needed.Hydrogen peroxide,a well-known green oxidant,is widely used in green hydrocarbon oxidation and nitridation.But its industrial production in China adopts fixed-bed technology,which is fall behind slurry-bed technology adopted by advanced foreign chemical companies,limiting the development of hydrogen peroxide industry and green hydrocarbon nitridation or oxidation industry.This article reviews the industrial production technologies of hydrogen peroxide and basic organic chemicals such as capro-lactam,aniline,propene oxide,epichlorohydrin,phenol,and benzenediol,especially introduces the green production technologies of basic organic chemicals related with H2O2.The article also emphasis on the efforts of Chinese researchers in developing its own slurry-bed technology of hydrogen peroxide produc-tion,and corresponding green hydrocarbon nitridation or oxidation technologies with hydrogen perox-ide.Compared with traditional nitridation or oxidation technologies,green production technologies of caprolactam,propene oxide,epichlorohydrin,and benzenediol with hydrogen peroxide promote the nitrogen atom utilization from 60％ to near 100％ and the carbon atom utilization from 80％ to near 100％.The waste emissions and environmental investments are reduced dramatically.Technological blockade against the green chemical industry of China are partially broken down,and technological upgrade in the chemical industry of China is guaranteed.
文献关键词：
中图分类号：
作者姓名：
Yanqiang Shi;Yuetong Xia;Guangtong Xu;Langyou Wen;Guohua Gao;Baoning Zong
作者机构：
State Key Laboratory of Catalytic Materials and Reaction Engineering,Research Institute of Petroleum Processing,Sinopec,Beijing 100083,China
文献出处：
引用格式：
[1]Yanqiang Shi;Yuetong Xia;Guangtong Xu;Langyou Wen;Guohua Gao;Baoning Zong-.Hydrogen peroxide and applications in green hydrocarbon nitridation and oxidation)[J].中国化学工程学报（英文版）,2022(01):145-161
A类：
nitrida,capro,caprolactam
B类：
Hydrogen,peroxide,applications,green,hydrocarbon,nitridation,oxidation,Basic,organic,chemicals,high,value,added,products,mainly,produced,by,However,several,drawbacks,traditional,technologies,future,such,complex,processes,poor,intrinsic,safety,low,atom,utilization,serious,environmental,pollution,urgently,needed,well,known,oxidant,widely,used,But,its,industrial,production,China,adopts,fixed,bed,technology,which,fall,behind,slurry,adopted,advanced,foreign,companies,limiting,development,hydrogen,industry,This,article,reviews,basic,aniline,propene,epichlorohydrin,phenol,benzenediol,especially,introduces,related,H2O2,also,emphasis,efforts,Chinese,researchers,developing,corresponding,Compared,promote,nitrogen,from,near,waste,emissions,investments,reduced,dramatically,Technological,blockade,against,partially,broken,down,technological,upgrade,guaranteed
AB值：
0.436834
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